| Brazil | 1 - 1 aet | Chile | ||
| David Luiz, Marcelo, Nerymar | (pens 3-2) | Aránguiz, Díaz | ||
| David Luiz 18 mins | (1-1) | Sánchez 32 mins | ||
| 12 Julio César | 01 Bravo | |||
| 02 Dani Alves Yellow card | 04 Isla | |||
| 06 Marcelo | 02 Mena Yellow card | |||
| 17 Luiz Gustavo Yellow card | 18 Jara | |||
| 03 Thiago Silva | 17 Medel (13 Rojas - 108' ) | |||
| 04 David Luiz | 05 Silva Yellow card | |||
| 07 Hulk Yellow card | 20 Aránguiz | |||
| 05 Fernandinho (16 Ramires - 72' ) | 21 Díaz | |||
| 09 Fred (21 Jô - 64' Yellow card) | 08 Vidal (09 Pinilla - 87' Yellow card) | |||
| 10 Neymar | 07 Sánchez | |||
| 11 Oscar (19 Willian - 105' ) | 11 Vargas (16 Gutierrez - 57' ) | |||
| Venue: Estádio Mineirão, Belo Horizonte | Date: 28th June 2014 | |||
| Referee: Howard Webb (England) | Round of 16 Game 1 | |||
| Attendance: 57,714 | Finals Match 49 | |||